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Self-assembled coordination thioether silver(I) macrocyclic complexes for homogeneous catalysis

  • Zhen Cao,
  • Aline Lacoudre,
  • Cybille Rossy and
  • Brigitte Bibal

Beilstein J. Org. Chem. 2019, 15, 2465–2472, doi:10.3762/bjoc.15.239

Graphical Abstract
  • of the two L2·(AgOTf)2 stereoisomers highlighted their different geometry. The catalytic activity of all silver(I) complexes was effective under homogeneous conditions in two tandem addition/cycloisomerization of alkynes using 0.5–1 mol % of catalytic loading. Keywords: coordination macrocycle
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Published 17 Oct 2019
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